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TitleMeasuring Spatially Resolved Collective Ionic Transport on Lithium Battery Cathodes Using Atomic Force Microscopy.
Publication TypeJournal Article
Year of Publication2017
AuthorsMascaro, Aaron, Zi Wang, Pierre Hovington, Yoichi Miyahara, Andrea Paolella, Vincent Gariepy, Zimin Feng, Tyler Enright, Connor Aiken, Karim Zaghib, Kirk H. Bevan, and Peter Grutter
JournalNano Lett
Volume17
Issue7
Pagination4489-4496
Date Published2017 Jul 12
ISSN1530-6992
Abstract

One of the main challenges in improving fast charging lithium-ion batteries is the development of suitable active materials for cathodes and anodes. Many materials suffer from unacceptable structural changes under high currents and/or low intrinsic conductivities. Experimental measurements are required to optimize these properties, but few techniques are able to spatially resolve ionic transport properties at small length scales. Here we demonstrate an atomic force microscope (AFM)-based technique to measure local ionic transport on LiFePOto correlate with the structural and compositional analysis of the same region. By comparing the measured values with density functional theory (DFT) calculations, we demonstrate that Coulomb interactions between ions give rise to a collective activation energy for ionic transport that is dominated by large phase boundary hopping barriers. We successfully measure both the collective activation energy and the smaller single-ion bulk hopping barrier and obtain excellent agreement with values obtained from our DFT calculations.

DOI10.1021/acs.nanolett.7b01857
Alternate JournalNano Lett.
PubMed ID28627889